| Season 1 | Episode 1 | Mr. Big | 1965-09-18 | 30 min |
| Season 1 | Episode 2 | Diplomat's Daughter | 1965-09-25 | 30 min |
| Season 1 | Episode 3 | School Days | 1965-10-02 | 30 min |
| Season 1 | Episode 4 | Our Man in Toyland | 1965-10-09 | 30 min |
| Season 1 | Episode 5 | Now You See Him... Now You Don't | 1965-10-16 | 30 min |
| Season 1 | Episode 6 | Washington 4, Indians 3 | 1965-10-23 | 30 min |
| Season 1 | Episode 7 | KAOS in CONTROL | 1965-10-30 | 30 min |
| Season 1 | Episode 8 | The Day Smart Turned Chicken | 1965-11-06 | 30 min |
| Season 1 | Episode 9 | Satan Place | 1965-11-13 | 30 min |
| Season 1 | Episode 10 | Our Man in Leotards | 1965-11-20 | 30 min |
| Season 1 | Episode 11 | Too Many Chiefs | 1965-11-27 | 30 min |
| Season 1 | Episode 12 | My Nephew the Spy | 1965-12-04 | 30 min |
| Season 1 | Episode 13 | Aboard the Orient Express | 1965-12-11 | 30 min |
| Season 1 | Episode 14 | Weekend Vampire | 1965-12-18 | 30 min |
| Season 1 | Episode 15 | Survival of the Fattest | 1965-12-25 | 30 min |
| Season 1 | Episode 16 | Double Agent | 1966-01-08 | 30 min |
| Season 1 | Episode 17 | Kisses for KAOS | 1966-01-15 | 30 min |
| Season 1 | Episode 18 | The Dead Spy Scrawls | 1966-01-22 | 30 min |
| Season 1 | Episode 19 | Back to the Old Drawing Board | 1966-01-29 | 30 min |
| Season 1 | Episode 20 | All in the Mind | 1966-02-05 | 30 min |
| Season 1 | Episode 21 | Dear Diary | 1966-02-12 | 30 min |
| Season 1 | Episode 22 | Smart, the Assassin | 1966-02-19 | 30 min |
| Season 1 | Episode 23 | I'm Only Human | 1966-02-26 | 30 min |
| Season 1 | Episode 24 | Stakeout on Blue Mist Mountain | 1966-03-05 | 30 min |
| Season 1 | Episode 25 | The Amazing Harry Hoo | 1966-03-12 | 30 min |
| Season 1 | Episode 26 | Hubert's Unfinished Symphony | 1966-03-19 | 30 min |
| Season 1 | Episode 27 | Ship of Spies (1) | 1966-04-02 | 30 min |
| Season 1 | Episode 28 | Ship of Spies (2) | 1966-04-09 | 30 min |
| Season 1 | Episode 29 | Shipment to Beirut | 1966-04-23 | 30 min |
| Season 1 | Episode 30 | The Last One in is a Rotten Spy | 1966-05-07 | 30 min |
| Season 2 | Episode 1 | Anatomy of a Lover | 1966-09-17 | 30 min |
| Season 2 | Episode 2 | Strike While the Agent is Hot | 1966-09-24 | 30 min |
| Season 2 | Episode 3 | A Spy for a Spy | 1966-10-01 | 30 min |
| Season 2 | Episode 4 | The Only Way to Die | 1966-10-08 | 30 min |
| Season 2 | Episode 5 | Maxwell Smart, Alias Jimmy Ballantine | 1966-10-15 | 30 min |
| Season 2 | Episode 6 | Casablanca | 1966-10-22 | 30 min |
| Season 2 | Episode 7 | The Decoy | 1966-10-29 | 30 min |
| Season 2 | Episode 8 | Hoo Done It | 1966-11-05 | 30 min |
| Season 2 | Episode 9 | Rub-a-Dub-Dub . . .Three Spies in a Sub | 1966-11-12 | 30 min |
| Season 2 | Episode 10 | The Greatest Spy on Earth | 1966-11-19 | 30 min |
| Season 2 | Episode 11 | Island of the Darned | 1966-11-26 | 30 min |
| Season 2 | Episode 12 | Bronzefinger | 1966-12-03 | 30 min |
| Season 2 | Episode 13 | Perils in a Pet Shop | 1966-12-10 | 30 min |
| Season 2 | Episode 14 | The Whole Tooth and . . . | 1966-12-24 | 30 min |
| Season 2 | Episode 15 | Kiss of Death | 1966-12-31 | 30 min |
| Season 2 | Episode 16 | It Takes One to Know One | 1967-01-07 | 30 min |
| Season 2 | Episode 17 | Someone Down Here Hates Me | 1967-01-14 | 30 min |
| Season 2 | Episode 18 | Cutback at CONTROL | 1967-01-21 | 30 min |
| Season 2 | Episode 19 | The Man from YENTA | 1967-01-28 | 30 min |
| Season 2 | Episode 20 | The Mummy | 1967-02-04 | 30 min |
| Season 2 | Episode 21 | The Girls from KAOS | 1967-02-11 | 30 min |
| Season 2 | Episode 22 | Smart Fit the Battle of Jericho | 1967-02-18 | 30 min |
| Season 2 | Episode 23 | Where-What-How-Who Am I? | 1967-02-25 | 30 min |
| Season 2 | Episode 24 | The Expendable Agent | 1967-03-04 | 30 min |
| Season 2 | Episode 25 | How to Succeed in the Spy Business Without Really Trying | 1967-03-11 | 30 min |
| Season 2 | Episode 26 | Appointment in Sahara | 1967-03-25 | 30 min |
| Season 2 | Episode 27 | Pussycats Galore | 1967-04-01 | 30 min |
| Season 2 | Episode 28 | A Man Called Smart (1) | 1967-04-08 | 30 min |
| Season 2 | Episode 29 | A Man Called Smart (2) | 1967-04-15 | 30 min |
| Season 2 | Episode 30 | A Man Called Smart (3) | 1967-04-22 | 30 min |
| Season 3 | Episode 1 | The Spy Who Met Himself | 1967-09-16 | 30 min |
| Season 3 | Episode 2 | Viva Smart | 1967-09-23 | 30 min |
| Season 3 | Episode 3 | Witness for the Persecution | 1967-10-07 | 30 min |
| Season 3 | Episode 4 | The Spirit is Willing | 1967-10-14 | 30 min |
| Season 3 | Episode 5 | Maxwell Smart, Private Eye | 1967-10-21 | 30 min |
| Season 3 | Episode 6 | Supersonic Boom | 1967-10-28 | 30 min |
| Season 3 | Episode 7 | One of Our Olives is Missing | 1967-11-04 | 30 min |
| Season 3 | Episode 8 | When Good Fellows Get Together | 1967-11-18 | 30 min |
| Season 3 | Episode 9 | Dr. Yes | 1967-11-25 | 30 min |
| Season 3 | Episode 10 | That Old Gang of Mine | 1967-12-02 | 30 min |
| Season 3 | Episode 11 | The Mild Ones | 1967-12-09 | 30 min |
| Season 3 | Episode 12 | Classification: Dead | 1967-12-23 | 30 min |
| Season 3 | Episode 13 | The Mysterious Dr. T | 1967-12-30 | 30 min |
| Season 3 | Episode 14 | The King Lives? | 1968-01-06 | 30 min |
| Season 3 | Episode 15 | The Groovy Guru | 1968-01-13 | 30 min |
| Season 3 | Episode 16 | The Little Black Book (1) | 1968-01-27 | 30 min |
| Season 3 | Episode 17 | The Little Black Book (2) | 1968-02-03 | 30 min |
| Season 3 | Episode 18 | Don't Look Back | 1968-02-10 | 30 min |
| Season 3 | Episode 19 | 99 Loses CONTROL | 1968-02-17 | 30 min |
| Season 3 | Episode 20 | The Wax Max | 1968-02-24 | 30 min |
| Season 3 | Episode 21 | Operation Ridiculous | 1968-03-02 | 30 min |
| Season 3 | Episode 22 | Spy, Spy, Birdie | 1968-03-09 | 30 min |
| Season 3 | Episode 23 | Run, Robot, Run | 1968-03-16 | 30 min |
| Season 3 | Episode 24 | The Hot Line | 1968-03-23 | 30 min |
| Season 3 | Episode 25 | Die, Spy | 1968-03-30 | 30 min |
| Season 3 | Episode 26 | The Reluctant Redhead | 1968-04-06 | 30 min |
| Season 4 | Episode 1 | The Impossible Mission | 1968-09-21 | 30 min |
| Season 4 | Episode 2 | Snoopy Smart vs. the Red Baron | 1968-09-28 | 30 min |
| Season 4 | Episode 3 | Closely Watched Planes | 1968-10-05 | 30 min |
| Season 4 | Episode 4 | The Secret of Sam Vittorio | 1968-10-12 | 30 min |
| Season 4 | Episode 5 | Diamonds Are a Spy's Best Friend | 1968-10-19 | 30 min |
| Season 4 | Episode 6 | The Worst Best Man | 1968-10-26 | 30 min |
| Season 4 | Episode 7 | A Tale of Two Tails | 1968-11-02 | 30 min |
| Season 4 | Episode 8 | The Return of the Ancient Mariner | 1968-11-09 | 30 min |
| Season 4 | Episode 9 | With Love and Twitches | 1968-11-16 | 30 min |
| Season 4 | Episode 10 | The Laser Blazer | 1968-11-30 | 30 min |
| Season 4 | Episode 11 | The Farkas Fracas | 1968-12-07 | 30 min |
| Season 4 | Episode 12 | Temporarily Out of CONTROL | 1968-12-14 | 30 min |
| Season 4 | Episode 13 | Schwartz's Island | 1968-12-21 | 30 min |
| Season 4 | Episode 14 | One Nation Invisible | 1968-12-28 | 30 min |
| Season 4 | Episode 15 | Hurray for Hollywood | 1969-01-04 | 30 min |
| Season 4 | Episode 16 | The Day They Raided the Knights | 1969-01-11 | 30 min |
| Season 4 | Episode 17 | Tequila Mockingbird | 1969-01-18 | 30 min |
| Season 4 | Episode 18 | I Shot 86 Today | 1969-02-01 | 30 min |
| Season 4 | Episode 19 | Absorb the Greek | 1969-02-08 | 30 min |
| Season 4 | Episode 20 | To Sire, with Love (1) | 1969-02-15 | 30 min |
| Season 4 | Episode 21 | To Sire, with Love (2) | 1969-02-22 | 30 min |
| Season 4 | Episode 22 | Shock It to Me | 1969-03-01 | 30 min |
| Season 4 | Episode 23 | Leadside | 1969-03-08 | 30 min |
| Season 4 | Episode 24 | Greer Window | 1969-03-15 | 30 min |
| Season 4 | Episode 25 | The Not-So-Great Escape (1) | 1969-03-22 | 30 min |
| Season 4 | Episode 26 | The Not-So-Great Escape (2) | 1969-03-29 | 30 min |
| Season 5 | Episode 1 | Pheasant Under Glass | 1969-09-26 | 30 min |
| Season 5 | Episode 2 | Ironhand | 1969-10-03 | 30 min |
| Season 5 | Episode 3 | Valerie of the Dolls | 1969-10-10 | 30 min |
| Season 5 | Episode 4 | Widow Often Annie | 1969-10-17 | 30 min |
| Season 5 | Episode 5 | The Treasure of C. Errol Madre | 1969-10-24 | 30 min |
| Season 5 | Episode 6 | Smart Fell on Alabama | 1969-10-31 | 30 min |
| Season 5 | Episode 7 | And Baby Makes Four (1) | 1969-11-07 | 30 min |
| Season 5 | Episode 8 | And Baby Makes Four (2) | 1969-11-14 | 30 min |
| Season 5 | Episode 9 | Physician Impossible | 1969-11-21 | 30 min |
| Season 5 | Episode 10 | The Apes of Rath | 1969-11-28 | 30 min |
| Season 5 | Episode 11 | Age Before Duty | 1969-12-05 | 30 min |
| Season 5 | Episode 12 | Is This Trip Necessary? | 1969-12-12 | 30 min |
| Season 5 | Episode 13 | Ice Station Siegfried | 1969-12-19 | 30 min |
| Season 5 | Episode 14 | Moonlighting Becomes You | 1970-01-02 | 30 min |
| Season 5 | Episode 15 | House of Max (1) | 1970-01-09 | 30 min |
| Season 5 | Episode 16 | House of Max (2) | 1970-01-16 | 30 min |
| Season 5 | Episode 17 | Rebecca of Funny-Folk Farm | 1970-01-23 | 30 min |
| Season 5 | Episode 18 | The Mess of Adrian Listenger | 1970-01-30 | 30 min |
| Season 5 | Episode 19 | Witness for the Execution | 1970-02-06 | 30 min |
| Season 5 | Episode 20 | How Green Was My Valet | 1970-02-13 | 30 min |
| Season 5 | Episode 21 | And Only Two Ninety-Nine | 1970-02-20 | 30 min |
| Season 5 | Episode 22 | Smartacus | 1970-02-27 | 30 min |
| Season 5 | Episode 23 | What's It All About, Algie? | 1970-04-24 | 30 min |
| Season 5 | Episode 24 | Hello, Columbus - Goodbye, America | 1970-05-01 | 30 min |
| Season 5 | Episode 25 | Do I Hear a Vaults? | 1970-05-08 | 30 min |
| Season 5 | Episode 26 | I Am Curiously Yellow | 1970-05-15 | 30 min |
